MSDS Number: B5628 * * * * * Effective Date: 05/19/08 * * * * * Supercedes: 08/24/05 BUFFER SOLUTIONS pH 6.86, pH 7.00, and pH 7.2


BUFFER SOLUTIONS pH 6.86, pH 7.00, and pH 7.2


1. Product Identification

Synonyms: Buffer Reference Solution pH 6.86; BuffARŽ pH 7.00 Concentrate; BuffARŽ pH 7.00; Phosphate Buffer Stock pH 7.2 (for Biochemical Oxygen Demand)
CAS No.: Not applicable to mixtures.
Molecular Weight: Not applicable to mixtures.
Chemical Formula: Not applicable.

2. Composition/Information on Ingredients


  Ingredient                                CAS No         Percent        Hazardous                                  
  ---------------------------------------   ------------   ------------   ---------   
 
  Mercury, (acetato-O)phenyl-               62-38-4           < 0.01%        No                                                                    
  Potassium Phosphate Monobasic             7778-77-0          < 1%          No                                                                  
  Potassium Phosphate Dibasic Anhydrous     7758-11-4          < 1%          No                                                                  
  Sodium Phosphate, Dibasic                 7558-79-4          < 1%          No                                                                  
  Water                                     7732-18-5           99%          No                                                                  
  Contains sodium or potassium salts at less than 1%. High pH gives rise to 
  hazards of product.
 

3. Hazards Identification

Emergency Overview
--------------------------
As part of good industrial and personal hygiene and safety procedure, avoid all unnecessary exposure to the chemical substance and ensure prompt removal from skin, eyes and clothing.

SAF-T-DATA(tm) Ratings (Provided here for your convenience)
-----------------------------------------------------------------------------------------------------------
Health Rating: 0 - None
Flammability Rating: 0 - None
Reactivity Rating: 0 - None
Contact Rating: 1 - Slight
Lab Protective Equip: GOGGLES; LAB COAT; PROPER GLOVES
Storage Color Code: Green (General Storage)
-----------------------------------------------------------------------------------------------------------

Potential Health Effects
----------------------------------

Inhalation:
No adverse health effects expected from inhalation.
Ingestion:
Large doses may cause stomach upset.
Skin Contact:
Not expected to be a health hazard from skin exposure. May cause mild irritation and redness.
Eye Contact:
Not expected to be a health hazard. May cause mild irritation, possible reddening.
Chronic Exposure:
No information found.
Aggravation of Pre-existing Conditions:
No information found.

4. First Aid Measures

Inhalation:
Not expected to require first aid measures.
Ingestion:
Not expected to require first aid measures. If large amounts were swallowed, give water to drink and get medical advice.
Skin Contact:
Not expected to require first aid measures. Wash exposed area with soap and water. Get medical advice if irritation develops.
Eye Contact:
Not expected to require first aid measures. Wash thoroughly with running water. Get medical advice if irritation develops.

5. Fire Fighting Measures

Fire:
Not considered to be a fire hazard.
Explosion:
Not considered to be an explosion hazard.
Fire Extinguishing Media:
Use any means suitable for extinguishing surrounding fire.
Special Information:
Use protective clothing and breathing equipment appropriate for the surrounding fire.

6. Accidental Release Measures

Ventilate area of leak or spill. Wear appropriate personal protective equipment as specified in Section 8. Contain and recover liquid when possible. Collect liquid in an appropriate container or absorb with an inert material (e. g., vermiculite, dry sand, earth), and place in a chemical waste container. Do not use combustible materials, such as saw dust. US Regulations (CERCLA) require reporting spills and releases to soil, water and air in excess of reportable quantities. The toll free number for the US Coast Guard National Response Center is (800) 424-8802.

7. Handling and Storage

Keep in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage, direct sunlight, and freezing. Containers of this material may be hazardous when empty since they retain product residues (vapors, liquid); observe all warnings and precautions listed for the product.

8. Exposure Controls/Personal Protection

Airborne Exposure Limits:
None established.
Ventilation System:
Not expected to require any special ventilation.
Personal Respirators (NIOSH Approved):
Not expected to require personal respirator usage.
Skin Protection:
Wear protective gloves and clean body-covering clothing.
Eye Protection:
Safety glasses.

9. Physical and Chemical Properties

Appearance:
Clear solution or yellow color coded solution.
Odor:
Odorless.
Solubility:
Soluble in water.
Specific Gravity:
ca. 1.0
pH:
6.86, 7.00 and 7.2
% Volatiles by volume @ 21C (70F):
No information found.
Boiling Point:
ca. 100C (ca. 212F)
Melting Point:
ca. 0C (ca. 32F)
Vapor Density (Air=1):
Essentially the same as water.
Vapor Pressure (mm Hg):
Essentially the same as water.
Evaporation Rate (BuAc=1):
Essentially the same as water.

10. Stability and Reactivity

Stability:
Stable under ordinary conditions of use and storage.
Hazardous Decomposition Products:
Phosphorus oxides may form when heated to decomposition.
Hazardous Polymerization:
Will not occur.
Incompatibilities:
No incompatibility data found.
Conditions to Avoid:
No information found.

11. Toxicological Information

  --------\Cancer Lists\------------------------------------------------------
                                         ---NTP Carcinogen---
  Ingredient                             Known    Anticipated    IARC Category
  ------------------------------------   -----    -----------    -------------
  Mercury, (acetato-O)phenyl-             No          No            None
  (62-38-4)
  Potassium Phosphate Monobasic           No          No            None
  (7778-77-0)
  Potassium Phosphate Dibasic             No          No            None
  Anhydrous (7758-11-4)
  Sodium Phosphate, Dibasic               No          No            None
  (7558-79-4)
  Water (7732-18-5)                       No          No            None

12. Ecological Information

Environmental Fate:
No information found.
Environmental Toxicity:
No information found.

13. Disposal Considerations

Dilute with water and flush to sewer if local ordinances allow, otherwise, whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements.

14. Transport Information

Not regulated.

15. Regulatory Information

  --------\Chemical Inventory Status - Part 1\---------------------------------
  Ingredient                                       TSCA  EC   Japan  Australia
  -----------------------------------------------  ----  ---  -----  ---------
  Mercury, (acetato-O)phenyl- (62-38-4)             Yes  Yes   Yes      Yes                                      
  Potassium Phosphate Monobasic (7778-77-0)         Yes  Yes   Yes      Yes                                      
  Potassium Phosphate Dibasic Anhydrous             Yes  Yes   Yes      Yes                                      
  (7758-11-4)
  Sodium Phosphate, Dibasic (7558-79-4)             Yes  Yes   Yes      Yes                                      
  Water (7732-18-5)                                 Yes  Yes   Yes      Yes                                      
 
  --------\Chemical Inventory Status - Part 2\---------------------------------
                                                          --Canada--
  Ingredient                                       Korea  DSL   NDSL  Phil.
  -----------------------------------------------  -----  ---   ----  -----
  Mercury, (acetato-O)phenyl- (62-38-4)             No    Yes   No     Yes                  
  Potassium Phosphate Monobasic (7778-77-0)         Yes   Yes   No     Yes                      
  Potassium Phosphate Dibasic Anhydrous             Yes   Yes   No     Yes                   
  (7758-11-4)
  Sodium Phosphate, Dibasic (7558-79-4)             Yes   Yes   No     Yes                  
  Water (7732-18-5)                                 Yes   Yes   No     Yes
 
  --------\Federal, State & International Regulations - Part 1\----------------
                                             -SARA 302-    ------SARA 313------
  Ingredient                                 RQ    TPQ     List  Chemical Catg.
  -----------------------------------------  ---   -----   ----  --------------
  Mercury, (acetato-O)phenyl- (62-38-4)      100   500*    No    Mercury comp
  Potassium Phosphate Monobasic (7778-77-0)  No    No      No         No
  Potassium Phosphate Dibasic Anhydrous      No    No      No         No
  (7758-11-4)
  Sodium Phosphate, Dibasic (7558-79-4)      No    No      No         No
  Water (7732-18-5)                          No    No      No         No
 
  --------\Federal, State & International Regulations - Part 2\----------------
                                                        -RCRA-    -TSCA-
  Ingredient                                 CERCLA     261.33     8(d) 
  -----------------------------------------  ------     ------    ------
  Mercury, (acetato-O)phenyl- (62-38-4)      100        P092       No                
  Potassium Phosphate Monobasic              No         No         No         
  (7778-77-0)
  Potassium Phosphate Dibasic Anhydrous      No         No         No                 
  (7758-11-4)
  Sodium Phosphate, Dibasic (7558-79-4)      5000       No         No                
  Water (7732-18-5)                          No         No         No                                                                
 
 
Chemical Weapons Convention:  No     TSCA 12(b):  No     CDTA:  No
SARA 311/312:  Acute: No       Chronic: No   Fire: No  Pressure: No
Reactivity: No          (Mixture / Liquid)
WARNING:
THIS PRODUCT CONTAINS A CHEMICAL(S) KNOWN TO THE STATE OF CALIFORNIA TO CAUSE BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.

Australian Hazchem Code: None allocated.
Poison Schedule: None allocated.
WHMIS:
This MSDS has been prepared according to the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR.

16. Other Information

NFPA Ratings: Health: 0 Flammability: 0 Reactivity: 0
Label Hazard Warning:
As part of good industrial and personal hygiene and safety procedure, avoid all unnecessary exposure to the chemical substance and ensure prompt removal from skin, eyes and clothing.
Label Precautions:
None.
Label First Aid:
Not applicable.
Product Use:
Industrial chemical.
Revision Information:
No Changes.
Disclaimer:
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Mallinckrodt Baker, Inc. provides the information contained herein in good faith but makes no representation as to its comprehensiveness or accuracy. This document is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose. MALLINCKRODT BAKER, INC. MAKES NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS OR IMPLIED, INCLUDING WITHOUT LIMITATION ANY WARRANTIES OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE WITH RESPECT TO THE INFORMATION SET FORTH HEREIN OR THE PRODUCT TO WHICH THE INFORMATION REFERS. ACCORDINGLY, MALLINCKRODT BAKER, INC. WILL NOT BE RESPONSIBLE FOR DAMAGES RESULTING FROM USE OF OR RELIANCE UPON THIS INFORMATION.
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Prepared by: Environmental Health & Safety
Phone Number: (314) 654-1600 (U.S.A.)