Synonyms: None
CAS No.: Not applicable to mixtures.
Molecular Weight: Not applicable to mixtures.
Chemical Formula: Not applicable to mixtures.
Product Codes: 4441, 4470
Ingredient CAS No Percent Hazardous --------------------------------------- ------------ ------------ --------- Citric Acid 77-92-9 65 - 80% Yes Flour N/A 20% Yes Bromothymol Blue Sodium Salt 34722-90-2 2% Yes Perlite 93763-70-3 9% Yes Silica, Amorphous 7631-86-9 2% Yes Specific CAS No. for Silica, Amorphous is 112945-52-5 (Amorphous fumed silica)
Emergency Overview
--------------------------
WARNING! CAUSES SEVERE EYE IRRITATION. CAUSES IRRITATION TO SKIN AND RESPIRATORY TRACT.
SAF-T-DATA(tm) Ratings (Provided here for your convenience)
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Health Rating: 2 - Moderate
Flammability Rating: 1 - Slight
Reactivity Rating: 1 - Slight
Contact Rating: 3 - Severe
Lab Protective Equip: GOGGLES & SHIELD; LAB COAT & APRON; VENT HOOD; PROPER GLOVES
Storage Color Code: Green (General Storage)
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Potential Health Effects
----------------------------------
Amorphous fumed silica does not contain crystalline silica.
Inhalation:
Causes irritation to the respiratory tract. Symptoms may include coughing, shortness of breath.
Ingestion:
Causes irritation to the gastrointestinal tract. Symptoms may include nausea, vomiting and diarrhea. Extremely large oral dosages may produce gastrointestinal disturbances. Calcium deficiency in blood may result in severe cases of ingestion.
Skin Contact:
Causes irritation to skin. Symptoms include redness, itching, and pain.
Eye Contact:
Highly irritating; may also be abrasive.
Chronic Exposure:
Chronic or heavy acute ingestion may cause tooth enamel erosion.
Aggravation of Pre-existing Conditions:
No information found.
Inhalation:
Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion:
Induce vomiting immediately as directed by medical personnel. Never give anything by mouth to an unconscious person.
Skin Contact:
Immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Eye Contact:
Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.
Fire:
Autoignition temperature: 1011C (1852F)
Autoignition temperature is for citric acid component. As with most organic solids, fire is possible at elevated temperatures or by contact with an ignition source.
Explosion:
Fine dust dispersed in air in sufficient concentrations, and in the presence of an ignition source is a potential dust explosion hazard.
Fire Extinguishing Media:
Water spray, dry chemical, alcohol foam, or carbon dioxide.
Special Information:
In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full facepiece operated in the pressure demand or other positive pressure mode.
Remove all sources of ignition. Ventilate area of leak or spill. Wear appropriate personal protective equipment as specified in Section 8. Spills: Clean up spills in a manner that does not disperse dust into the air. Use non-sparking tools and equipment. Reduce airborne dust and prevent scattering by moistening with water. Pick up spill for recovery or disposal and place in a closed container.
Keep in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage. Containers of this material may be hazardous when empty since they retain product residues (dust, solids); observe all warnings and precautions listed for the product.
Airborne Exposure Limits:
Silica (synthetic, amorphous):
- OSHA Permissible Exposure Limit (PEL) -
80/(%SiO2) mg/m3 (TWA) for amorphous silica, including natural diatomaceous earth.
Perlite:
-OSHA Permissible Exposure Limit (PEL):
15 mg/m3 (total dust), 5 mg/m3 (respirable fraction)
Ventilation System:
A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details.
Personal Respirators (NIOSH Approved):
For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator (NIOSH type N95 or better filters) may be worn. If oil particles (e.g. lubricants, cutting fluids, glycerine, etc.) are present, use a NIOSH type R or P filter. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator. WARNING: Air-purifying respirators do not protect workers in oxygen-deficient atmospheres.
Skin Protection:
Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact.
Eye Protection:
Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Appearance:
Yellow crystals or powder.
Odor:
Odorless.
Solubility:
Slight (0.1-1%)
Specific Gravity:
No information found.
pH:
No information found.
% Volatiles by volume @ 21C (70F):
0
Boiling Point:
No information found.
Melting Point:
No information found.
Vapor Density (Air=1):
Not applicable.
Vapor Pressure (mm Hg):
Not applicable.
Evaporation Rate (BuAc=1):
No information found.
Stability:
Stable under ordinary conditions of use and storage.
Hazardous Decomposition Products:
Bromines and oxides of carbon, silicon and sulfur.
Hazardous Polymerization:
Will not occur.
Incompatibilities:
For Citric Acid: Metal nitrates (potentially explosive reaction), alkali carbonates and bicarbonates, potassium tartrate. Will corrode copper, zinc, aluminum and their alloys. For Perlite: hydrogen fluoride. For Bromothymol Blue Sodium Salt: strong oxidizers.
Conditions to Avoid:
Heat, flame, ignition sources, dusting, moisture and incompatibles.
Toxicological Data:
For Citric Acid: Oral rat LD50: 3 g/kg; irritation skin rabbit: 500 mg/24H mild; eye rabbit: 750 ug/24H severe. For amorphous fumed silica: oral rat LD50: 3160 mg/kg. Investigated as a tumorigen and mutagen. For perlite: oral mouse LD50: 12,960 mg/kg.
Carcinogenicity:
IARC category for silica, amorphous (7631-86-9) applies to silicas that may contain crystalline silica. The silica in this product is synthetic and does not contain crystalline silica.
--------\Cancer Lists\------------------------------------------------------
---NTP Carcinogen---
Ingredient Known Anticipated IARC Category
------------------------------------ ----- ----------- -------------
Citric Acid (77-92-9) No No None
Flour No No None
Bromothymol Blue Sodium Salt No No None
(34722-90-2)
Perlite (93763-70-3) No No None
Silica, Amorphous (7631-86-9) No No 3
Environmental Fate:
No information found.
Environmental Toxicity:
No information found.
Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements.
Not regulated.
--------\Chemical Inventory Status - Part 1\---------------------------------
Ingredient TSCA EC Japan Australia
----------------------------------------------- ---- --- ----- ---------
Citric Acid (77-92-9) Yes Yes Yes Yes
Flour Yes Yes Yes Yes
Bromothymol Blue Sodium Salt (34722-90-2) Yes Yes No Yes
Perlite (93763-70-3) Yes No No Yes
Silica, Amorphous (7631-86-9) Yes Yes Yes Yes
--------\Chemical Inventory Status - Part 2\---------------------------------
--Canada--
Ingredient Korea DSL NDSL Phil.
----------------------------------------------- ----- --- ---- -----
Citric Acid (77-92-9) Yes Yes No Yes
Flour Yes Yes No Yes
Bromothymol Blue Sodium Salt (34722-90-2) No Yes No Yes
Perlite (93763-70-3) No Yes No Yes
Silica, Amorphous (7631-86-9) Yes Yes No Yes
--------\Federal, State & International Regulations - Part 1\----------------
-SARA 302- ------SARA 313------
Ingredient RQ TPQ List Chemical Catg.
----------------------------------------- --- ----- ---- --------------
Citric Acid (77-92-9) No No No No
Flour No No No No
Bromothymol Blue Sodium Salt (34722-90-2) No No No No
Perlite (93763-70-3) No No No No
Silica, Amorphous (7631-86-9) No No No No
--------\Federal, State & International Regulations - Part 2\----------------
-RCRA- -TSCA-
Ingredient CERCLA 261.33 8(d)
----------------------------------------- ------ ------ ------
Citric Acid (77-92-9) No No No
Flour No No No
Bromothymol Blue Sodium Salt No No No
(34722-90-2)
Perlite (93763-70-3) No No No
Silica, Amorphous (7631-86-9) No No No
Chemical Weapons Convention: No TSCA 12(b): No CDTA: No
SARA 311/312: Acute: Yes Chronic: Yes Fire: No Pressure: No
Reactivity: No (Mixture / Solid)
Australian Hazchem Code: None allocated.
Poison Schedule: None allocated.
WHMIS:
This MSDS has been prepared according to the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR.
NFPA Ratings: Health: 2 Flammability: 1 Reactivity: 0
Label Hazard Warning:
WARNING! CAUSES SEVERE EYE IRRITATION. CAUSES IRRITATION TO SKIN AND RESPIRATORY TRACT.
Label Precautions:
Avoid contact with eyes, skin and clothing.
Avoid breathing dust.
Keep container closed.
Use only with adequate ventilation.
Wash thoroughly after handling.
Label First Aid:
In case of contact, immediately flush eyes or skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Wash clothing before reuse. If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. In all cases, get medical attention.
Product Use:
Spill Clean-Up
Revision Information:
MSDS Section(s) changed since last revision of document include: 8.
Disclaimer:
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Mallinckrodt Baker, Inc. provides the information contained herein in good faith but makes no representation as to its comprehensiveness or accuracy. This document is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose. MALLINCKRODT BAKER, INC. MAKES NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS OR IMPLIED, INCLUDING WITHOUT LIMITATION ANY WARRANTIES OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE WITH RESPECT TO THE INFORMATION SET FORTH HEREIN OR THE PRODUCT TO WHICH THE INFORMATION REFERS. ACCORDINGLY, MALLINCKRODT BAKER, INC. WILL NOT BE RESPONSIBLE FOR DAMAGES RESULTING FROM USE OF OR RELIANCE UPON THIS INFORMATION.
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Prepared by: Environmental Health & Safety
Phone Number: (314) 654-1600 (U.S.A.)