MSDS Number: T4770 * * * * * Effective Date: 02/18/03 * * * * * Supercedes: 05/08/00 Tricaprylmethylammonium Chloride


Tricaprylmethylammonium Chloride


1. Product Identification

Synonyms: None
CAS No.: 5137-55-3
Molecular Weight: 404.17
Chemical Formula: (C8H17)3N(CH3)Cl
Product Codes: W450

2. Composition/Information on Ingredients


  Ingredient                                CAS No         Percent        Hazardous                                  
  ---------------------------------------   ------------   ------------   ---------   
 
  TricaprylmethylammoniumChloride           5137-55-3        80 - 100%       Yes                                                                    
 

3. Hazards Identification

Emergency Overview
--------------------------
DANGER! CAUSES SEVERE SKIN AND EYE BURNS. HARMFUL IF SWALLOWED OR INHALED. TARGET ORGAN(S):Eyes, skin, mucous membranes.

Potential Health Effects
----------------------------------

Inhalation:
Is harmful
Ingestion:
Burns to mouth, throat, and stomach.
Skin Contact:
Severe burns.
Eye Contact:
Severe burns.
Chronic Exposure:
No information found.
Aggravation of Pre-existing Conditions:
Damaged skin.

4. First Aid Measures

Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Prompt action is essential.
Ingestion:
If swallowed, DO NOT INDUCE VOMITING. Give large quantities of water. Never give anything by mouth to an unconscious person. Get medical attention immediately.
Skin Contact:
In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before re-use.
Eye Contact:
In case of eye contact, immediately flush with plenty of water for at least 15 minutes.

5. Fire Fighting Measures

Fire:
Flash point: 102C (216F) CC
Explosion:
Fire or excessive heat may produce hazardous decomposition products.
Fire Extinguishing Media:
Water spray; Dry chemical; Carbon dioxide.
Special Information:
Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes.

6. Accidental Release Measures

Absorb material in sand or other suitable absorbent and place in container.



7. Handling and Storage

Keep from contact with oxidizing materials. Containers of this material may be hazardous when empty since they retain product residues (vapors, liquid); observe all warnings and precautions listed for the product.

8. Exposure Controls/Personal Protection

Airborne Exposure Limits:
None established.
Ventilation System:
A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details.
Personal Respirators (NIOSH Approved):
For conditions of use where exposure to the substance is apparent and engineering controls are not feasble, consult an industrial hygienist. For emergencies, or instances where the exposure levels are not known, use a full-facepiece positive-pressure, air-supplied respirator. WARNING: Air purifying respirators do not protect workers in oxygen-deficient atmospheres.
Skin Protection:
Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact.
Eye Protection:
Use chemical safety goggles and/or a full face shield where splashing is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures:
There is insufficient data in the published literature to assign complete numerical SAF-T-DATA* ratings and laboratory protective equipment for this product. Special precautions must be used in storage, use and handling. Protective equipment for laboratory bench use should be chosen using professional judgment based on the size and type of reaction or test to be conducted and the available ventilation, with overriding consideration to minimize contact with the chemical.

9. Physical and Chemical Properties

Appearance:
Clear reddish brown liquid.
Odor:
No information found.
Solubility:
Appreciable (> 10%)
Specific Gravity:
No information found.
pH:
No information found.
% Volatiles by volume @ 21C (70F):
0
Boiling Point:
225C (437F)
Melting Point:
No information found.
Vapor Density (Air=1):
No information found.
Vapor Pressure (mm Hg):
0 @ 20C (68F)
Evaporation Rate (BuAc=1):
0

10. Stability and Reactivity

Stability:
Stable under ordinary conditions of use and storage.
Hazardous Decomposition Products:
Carbon dioxide, carbon monoxide, oxides of nitrogen, Hydrogen chloride gas
Hazardous Polymerization:
Will not occur.
Incompatibilities:
Strong oxidizing agents.
Conditions to Avoid:
No information found.

11. Toxicological Information

  --------\Cancer Lists\------------------------------------------------------
                                         ---NTP Carcinogen---
  Ingredient                             Known    Anticipated    IARC Category
  ------------------------------------   -----    -----------    -------------
  TricaprylmethylammoniumChloride         No          No            None
  (5137-55-3)

12. Ecological Information

Environmental Fate:
No information found.
Environmental Toxicity:
No information found.

13. Disposal Considerations

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste facility. Although not a listed RCRA hazardous waste, this material may exhibit one or more characteristics of a hazardous waste and require appropriate analysis to determine specific disposal requirements. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements.

14. Transport Information

Domestic (Land, D.O.T.)
-----------------------
Proper Shipping Name: CORROSIVE LIQUID, N.O.S. (TRICAPRYLMETHYLAMMONIUM CHLORIDE)
Hazard Class: 8
UN/NA: UN1760
Packing Group: II
Information reported for product/size: 500G

International (Water, I.M.O.)
-----------------------------
Proper Shipping Name: CORROSIVE LIQUID, N.O.S. (TRICAPRYLMETHYLAMMONIUM CHLORIDE)
Hazard Class: 8
UN/NA: UN1760
Packing Group: II
Information reported for product/size: 500G


15. Regulatory Information

  --------\Chemical Inventory Status - Part 1\---------------------------------
  Ingredient                                       TSCA  EC   Japan  Australia
  -----------------------------------------------  ----  ---  -----  ---------
  TricaprylmethylammoniumChloride (5137-55-3)       Yes  Yes   Yes      Yes                                      
 
  --------\Chemical Inventory Status - Part 2\---------------------------------
                                                          --Canada--
  Ingredient                                       Korea  DSL   NDSL  Phil.
  -----------------------------------------------  -----  ---   ----  -----
  TricaprylmethylammoniumChloride (5137-55-3)       Yes   No    No     Yes                        
 
  --------\Federal, State & International Regulations - Part 1\----------------
                                             -SARA 302-    ------SARA 313------
  Ingredient                                 RQ    TPQ     List  Chemical Catg.
  -----------------------------------------  ---   -----   ----  --------------
  TricaprylmethylammoniumChloride (5137-55-3)No    No      No         No
 
  --------\Federal, State & International Regulations - Part 2\----------------
                                                        -RCRA-    -TSCA-
  Ingredient                                 CERCLA     261.33     8(d) 
  -----------------------------------------  ------     ------    ------
  TricaprylmethylammoniumChloride            No         No         No           
  (5137-55-3)
 
 
Chemical Weapons Convention:  No     TSCA 12(b):  No     CDTA:  No
SARA 311/312:  Acute: Yes      Chronic: Yes  Fire: No  Pressure: No
Reactivity: No          (Pure / Liquid)


Australian Hazchem Code: None allocated.
Poison Schedule: None allocated.
WHMIS:
This MSDS has been prepared according to the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR.

16. Other Information

Label Hazard Warning:
DANGER! CAUSES SEVERE SKIN AND EYE BURNS. HARMFUL IF SWALLOWED OR INHALED. TARGET ORGAN(S):Eyes, skin, mucous membranes.
Label Precautions:
No SAF-T-DATA Ratings have been developed for this product. Read and follow all warnings, precautions, instructions and other safety and handling information on the label and MSDS.
Avoid contact with eyes, skin, clothing.
Do not breathe vapor. Use only with adequate ventilation. Keep container closed. Wash thoroughly after handling.
Label First Aid:
If swallowed, DO NOT INDUCE VOMITING. Give large quantities of water. Never give anything by mouth to an unconscious person. If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Prompt action is essential. In case of contact, immediately flush eyes or skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Product Use:
Laboratory Reagent.
Revision Information:
MSDS Section(s) changed since last revision of document include: 8.
Disclaimer:
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Mallinckrodt Baker, Inc. provides the information contained herein in good faith but makes no representation as to its comprehensiveness or accuracy. This document is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose. MALLINCKRODT BAKER, INC. MAKES NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS OR IMPLIED, INCLUDING WITHOUT LIMITATION ANY WARRANTIES OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE WITH RESPECT TO THE INFORMATION SET FORTH HEREIN OR THE PRODUCT TO WHICH THE INFORMATION REFERS. ACCORDINGLY, MALLINCKRODT BAKER, INC. WILL NOT BE RESPONSIBLE FOR DAMAGES RESULTING FROM USE OF OR RELIANCE UPON THIS INFORMATION.
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Prepared by: Environmental Health & Safety
Phone Number: (314) 654-1600 (U.S.A.)